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储能系统技术 储能系统 SiC器件 ★ 5.0

尖晶石铁酸钴锚定聚吡咯复合材料作为储能应用阴极材料的电化学研究

Electrochemical investigation on spinel cobalt ferrite anchored polypyrrole composite as a cathode material for energy storage applications

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中文摘要

在本研究中,通过一种简单的原位化学氧化聚合方法合成了铁酸钴@聚吡咯(CoFe₂O₄@PPy)纳米复合材料,并将这种简便制备的聚合物纳米复合材料(PNC)电极用于电化学储能应用。对所制备纳米复合材料的物理和电化学性能进行了表征。所制备PNC电极的电化学性能在6 M KOH水溶液电解质中进行了研究。该PNC被制备成电极并在双电极系统中进行测试,在2 A g⁻¹的电流密度下获得了69.63 F g⁻¹的比电容。所制备的器件在经过20000次GCD循环后仍表现出优异的循环稳定性(68.86%),并在25 A g⁻¹的电流密度下实现了24.75 Wh kg⁻¹的高能量密度和4255.28 W kg⁻¹的优异功率密度。

English Abstract

In this work, cobalt ferrite@polypyrrole (CoFe₂O₄@PPy) nanocomposites have been synthesized by a simple in-situ chemical oxidative polymerization process and this facile polymer nanocomposite (PNC) electrodes have been utilized for electrochemical energy storage applications. The physical and electrochemical properties of the nanocomposite has been characterized. The electrochemical properties of the prepared PNC electrode have been investigated in 6 M KOH aqueous electrolyte. This PNC has been fabricated as an electrode and examined in a two-electrode system, which has obtained a specific capacitance of 69.63 F g⁻ 1 at current density of 2 A g −1 . The fabricated device has an excellent cyclic stability of 68.86% after GCD 20000 cycles and a superior energy density of 24.75 Wh kg −1 and an excellent power density of 4255.28 W kg −1 at a current density of 25 A g −1 .
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SunView 深度解读

该钴铁氧体@聚吡咯复合材料展现出优异的电化学储能性能,其24.75 Wh/kg能量密度和4255.28 W/kg功率密度对阳光电源ST系列储能变流器和PowerTitan储能系统具有参考价值。该材料在20000次循环后仍保持68.86%容量保持率,为我司储能系统电极材料优化提供新思路。其高倍率性能特性可应用于充电桩快充场景,提升功率响应速度。建议关注此类导电聚合物复合材料在储能PCS直流侧电容及辅助储能单元的应用潜力,配合SiC器件可进一步提升系统功率密度和循环寿命。