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光伏发电技术 储能系统 SiC器件 ★ 5.0

磁控溅射NiOx用于钙钛矿太阳能电池

Magnetron sputtering NiOx for perovskite solar cells

作者 Xiangyi ShenXinwu KeYingdong XiaQingxun GuoYonghua Chen
期刊 半导体学报
出版日期 2025年1月
卷/期 第 46 卷 第 5 期
技术分类 光伏发电技术
技术标签 储能系统 SiC器件
相关度评分 ★★★★★ 5.0 / 5.0
关键词 Xiangyi Shen Xinwu Ke Yingdong Xia Qingxun Guo Yonghua Chen 半导体学报(英文版) Journal of Semiconductors
语言:

中文摘要

钙钛矿太阳能电池(PSCs)因其优异的光电转换效率和低成本制造潜力成为可再生能源领域的研究热点。空穴传输层(HTL)是PSCs的关键组成部分,显著影响器件整体性能。磁控溅射NiOx因具有高载流子迁移率、优异稳定性及适用于大规模生产而备受关注。本文综述了磁控溅射NiOx作为PSCs空穴传输层的研究进展,系统总结了其薄膜基本特性、溅射工艺中影响光电性能的关键参数及相应器件性能,并重点探讨了NiOx与钙钛矿界面问题及其修饰策略。最后,分析了该技术面临的挑战与未来发展方向。

English Abstract

Perovskite solar cells(PSCs)have become a hot topic in the field of renewable energy due to their excellent power conversion efficiency and potential for low-cost manufacturing.The hole transport layer(HTL),as a key component of PSCs,plays a crucial role in the cell's overall performance.Magnetron sputtering NiOx has attracted widespread attention due to its high carrier mobility,excellent stability,and suitability for large-scale production.Herein,an insightful summary of the recent progress of magnetron sputtering NiOx as the HTL of PSCs is presented to promote its further development.This review summa-rized the basic properties of magnetron sputtering NiOx thin film,the key parameters affecting the optoelectronic properties of NiOx thin films during the magnetron-sputtering process,and the performance of the corresponding PSCs.Special attention was paid to the interfacial issues between NiOx and perovskites,and the modification strategies were systematically summa-rized.Finally,the challenges of sputtering NiOx technology and the possible development opportunities were concluded and dis-cussed.
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SunView 深度解读

该磁控溅射NiOx技术对阳光电源光伏产品线具有前瞻性参考价值。虽然当前SG系列逆变器主要配套晶硅组件,但钙钛矿电池的高效率、低成本特性符合光伏平价上网趋势。磁控溅射工艺的大规模生产适配性与阳光电源规模化制造能力高度契合。该技术在空穴传输层的界面优化思路可借鉴至功率器件封装界面设计,特别是SiC器件的界面钝化处理。此外,钙钛矿电池的稳定性提升对户用储能系统ST系列的长寿命要求具有启发意义。建议跟踪钙钛矿商业化进程,评估其在分布式光伏及光储一体化系统中的应用潜力,为未来产品技术路线储备提供参考。