← 返回
光伏发电技术 SiC器件 ★ 5.0

利用热气流辅助退火改善卤化铅钙钛矿薄膜及器件性能

Improved Lead Halide Perovskite Films and Devices Using Hot-Flow-Assisted Annealing

作者 Ali Baghban Parashkouh · Ali Sadr · Maryam Heidariramsheh · Nima Taghavinia
期刊 IEEE Journal of Photovoltaics
出版日期 2025年3月
技术分类 光伏发电技术
技术标签 SiC器件
相关度评分 ★★★★★ 5.0 / 5.0
关键词 卤化铅钙钛矿薄膜 钙钛矿太阳能电池 热干空气流 表面缺陷 功率转换效率
语言:

中文摘要

对卤化铅钙钛矿薄膜的物理与化学调控对于降低缺陷密度、提升钙钛矿太阳能电池的性能和稳定性至关重要。本研究探索了在热板退火过程中引入热干空气气流的工艺。结果表明,该方法可获得更平整的薄膜形貌并减少表面缺陷。当热干空气流量为15 L/min时,器件光电转换效率从13.56%提升至15.31%,填充因子和短路电流密度分别提高约4.3%和10.4%。然而,过高的气流速率会导致大面积孔洞形成,引发漏电流增加和器件性能退化。

English Abstract

Physical and chemical controlling of the lead halide perovskite films is crucial to minimize defects and improve overall performance and stability of perovskite solar cells. In this study, applying a hot flow of dry air on the surface of perovskite films during hot plate annealing is investigated. We found that this technique leads to a smooth texture and reduces the surface defects. A hot dry airflow of 15 L/min improves the power conversion efficiency from 13.56% to 15.31%, with approximately 4.3% and 10.4% enhancement of fill factor and short-circuit current density, respectively. However, increasing the rate of dry airflow leads to large voids, which is a critical concern for leakage current and performance degradation.
S

SunView 深度解读

该热气流辅助退火技术对阳光电源光伏产业链具有重要应用价值。研究表明优化退火工艺可使钙钛矿电池效率从13.56%提升至15.31%,填充因子和短路电流密度分别提高4.3%和10.4%,这为SG系列光伏逆变器的上游组件性能提升提供了技术路径。更平整的薄膜形貌和更低的表面缺陷密度可提高组件长期稳定性,直接影响iSolarCloud平台的发电量预测精度和系统全生命周期收益。该工艺对温度和气流速率的精确控制要求,与阳光电源在功率器件热管理和环境适应性设计方面的技术积累高度契合,可为钙钛矿-晶硅叠层电池等新型高效组件的规模化应用提供制造工艺参考。