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光伏发电技术 GaN器件 ★ 5.0

具有AlGaN应变补偿层的InGaN激光光伏电池在450 nm激光照射下的性能提升

Performance Enhancement of InGaN Laser Photovoltaic Cell With AlGaN Strain Compensation Layer Irradiated by 450 nm Laser

作者 Heng-Sheng Shan · Yi-Xin Wang · Cheng-Ke Li · Ning Wang · Xiao-Ya Li · Shu-Fang Ma
期刊 IEEE Journal of Photovoltaics
出版日期 2024年11月
技术分类 光伏发电技术
技术标签 GaN器件
相关度评分 ★★★★★ 5.0 / 5.0
关键词 氮化铟镓激光光伏电池 氮化铝镓应变补偿层 光电转换效率 晶体质量 应力调控
语言:

中文摘要

通过在(0001)取向的图案化蓝宝石衬底(PSS)上生长铝镓氮(AlGaN)应变补偿层(SCL),研制出一种高效的氮化铟镓(InGaN)激光光伏电池(LPVC),其光电转换效率(η)达到了23.09%。光致发光光谱证实,插入AlGaN SCL后,峰值分裂现象减少,表明铟(In)分布更加均匀。此外,样品的半高宽变窄,这表明插入AlGaN SCL后晶体质量得到了改善。X射线衍射分析显示,AlGaN SCL能有效调节InGaN材料中的应变弛豫,与未采用AlGaN SCL的材料相比,有源区中阱与垒之间的界面陡峭度得到增强。此外,拉曼分析表明,InGaN材料中氮化镓(GaN)的压应力得到进一步释放,这充分验证了引入AlGaN SCL的应力调控模型。最后,将材料参数引入Silvaco软件进行模拟,模拟结果与实验结果的误差小于2%,证实了SCL在提高效率方面的关键作用。本文为高效InGaN LPVC的器件设计优化提供了有价值的见解。

English Abstract

A high-efficiency indium gallium nitride (InGaN) laser photovoltaic cell (LPVC) was demonstrated to achieve a photoelectric conversion efficiency (η) of 23.09% by incorporating an AlGaN strain compensation layer (SCL) grown on a (0001)-oriented patterned sapphire substrate (PSS). The photoluminescence spectra confirm that the peak splitting is reduced after the insertion of AlGaN SCL, indicating a more uniform distribution of In. In addition, the full width at half maximum of the sample is narrowed, indicating that the crystal quality is improved after the insertion of AlGaN SCL. The X-ray diffraction analysis reveals the effective modulation of strain relaxation in InGaN materials by the AlGaN SCL, enhancing steepness of the interface between the well and the barrier in the active region compared with materials without the AlGaN SCL. Furthermore, Raman analysis shows an additional release of GaN compressive stress in InGaN materials, providing full validation for the stress regulation model from introducing the AlGaN SCL. Finally, introducing material parameters into Silvaco software resulted in simulation and experimental errors of less than 2%, the critical role of SCL in efficiency improvement is validated. Valuable insights on optimizing device design for high-efficiency InGaN LPVCs are provided.
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SunView 深度解读

该InGaN激光光伏技术对阳光电源的功率器件研发具有重要参考价值。研究中AlGaN应变补偿层降低缺陷密度的设计思路,可借鉴至SiC/GaN功率器件的异质外延优化,改善SG系列逆变器和ST储能变流器中GaN器件的晶格失配问题,提升器件可靠性。23.09%的光电转换效率验证了应变工程在III-V族半导体中的有效性,为阳光电源开发高效率GaN功率模块提供了材料层面的优化方案。该应变补偿技术可应用于降低GaN HEMT器件的缺陷态密度,提升开关特性,助力1500V高压系统和充电桩产品的功率密度提升与损耗优化。