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储能系统技术 储能系统 工商业光伏 ★ 5.0

大型多级金属氢化物氢气压缩机的实验研究与性能评估

Experimental study and performance evaluation of a large-scale multistage metal hydride-based hydrogen compressor

作者 Abhishek Pari · Alok Kumar · Palanisamy Muthukumar · Amaresh Dalal · Shanta Kumar
期刊 Applied Energy
出版日期 2025年1月
卷/期 第 390 卷
技术分类 储能系统技术
技术标签 储能系统 工商业光伏
相关度评分 ★★★★★ 5.0 / 5.0
关键词 Reported thermally driven metal hydride hydrogen compressor.
语言:

中文摘要

氢气作为清洁能源载体,对可持续能源未来至关重要。高效的压缩技术对其有效储存与运输具有关键作用。本研究详细阐述了一种工业级绿色氢气压缩系统的研制过程,该系统采用金属氢化物氢气压缩机(MHHC),并集成可再生热能系统。该系统利用低于100°C的低温热源,可将氢气从初始压力10–20 bar压缩至超过250 bar。在本研究中,共将550 g氢气在反应器内通过三个阶段压缩至300 bar,操作温度范围为5–91.2 °C,因此适用于与太阳能热系统耦合应用。第一级反应器装有25 kg La0.8Ce0.2Ni5,在44.6分钟内吸收了307 g氢气,并向第二级反应器转移了288 g氢气(可逆性达93.8%),第二级反应器含有等质量的La0.5Ce0.5Ni4Fe材料。最终,275.5 g氢气被转移至第三级反应器,其材料为Ti0.8Zr0.2CrMn0.3Fe0.6Ni0.1。随后将所吸附的氢气加热至91.2 °C,以达到300 bar的压力。系统完成一次针对275.5 g氢气的压缩循环需消耗36.2 MJ(10.1 kWh)的热能,实现约5%的第一定律效率。在采用所开发的MHHC系统的加氢站(HRS)中,将一个I型氢气瓶充装至155 bar需要四次充装过程,累计转移约466 g氢气,耗时34.34分钟。

English Abstract

Abstract Hydrogen is crucial for a sustainable energy future, serving as a clean energy carrier. Efficient compression is vital for its effective storage and transport. This study details the design and development of an industrial-scale setup for green hydrogen compression using a Metal Hydride Hydrogen Compressor (MHHC) integrated with renewable thermal system. The system is designed to compress hydrogen from an initial pressure of 10–20 bar to over 250 bar, utilizing thermal energy inputs available at temperature below 100 °C. In this study, 550 g of hydrogen was compressed to 300 bar within the reactor in three stages between the temperature range of 5–91.2 °C, making it suitable for coupling with solar thermal systems . The stage 1 reactor, containing 25 kg of La 0.8 Ce 0.2 Ni 5 , absorbed 307 g of hydrogen in 44.6 min and transferred 288 g (93.8% reversibility) to the stage 2 reactor, which contained an equivalent mass of La 0.5 Ce 0.5 Ni 4 Fe. Finally, 275.5 g of hydrogen was transferred to the stage 3 reactor, consisting of Ti 0.8 Zr 0.2 CrMn 0.3 Fe 0.6 Ni 0.1 . The absorbed hydrogen was then heated to 91.2 °C to attain a pressure of 300 bar. The system required 36.2 MJ (10.1 kWh) of thermal energy to complete one compression cycle for 275.5 g of hydrogen, achieving a first law efficiency of ∼5%. At a Hydrogen Refueling Station (HRS) using the developed MHHC system, refilling a Type I H 2 cylinder up to 155 bar would require four refills transferring about 466 g of hydrogen in 34.34 min.
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SunView 深度解读

该金属氢化物压缩技术为阳光电源绿氢储能系统提供创新方向。可与ST系列储能变流器和SG光伏逆变器耦合,利用<100°C低品位余热实现10-300bar氢压缩,首级效率5%。适配工商业光伏场景:PowerTitan储能系统可提供热管理能量,iSolarCloud平台可优化三级压缩循环控制。该技术可拓展至加氢站解决方案,与阳光充电桩形成氢-电混合能源网络,提升可再生能源消纳能力和系统经济性。