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光伏发电技术
★ 5.0
基于ZnTe:N/IWO复合透明背电极的双面超薄CdTe太阳能电池研究
Study on the Bifacial Ultrathin CdTe Solar Cell With ZnTe:N/IWO Composite Transparent Back Electrode
| 作者 | Xin Zhang · Xiutao Yang · Yujie Zheng · Yunpu Tai · Jingquan Zhang · Bing Li |
| 期刊 | IEEE Journal of Photovoltaics |
| 出版日期 | 2024年10月 |
| 技术分类 | 光伏发电技术 |
| 相关度评分 | ★★★★★ 5.0 / 5.0 |
| 关键词 | 双面半透明太阳能电池 碲化镉 多晶薄膜 背照转换效率 复合透明背电极 |
语言:
中文摘要
双面半透明太阳能电池的制备是建筑集成光伏技术发展和叠层太阳能电池构建的一项有前景的技术。在本工作中,利用近空间升华系统制备了厚度为 1 微米的碲化镉(CdTe)多晶薄膜,同时分别采用磁控溅射和反应等离子体沉积技术沉积了氮掺杂碲化锌(ZnTe:N)层和钨掺杂氧化铟(IWO)层。在分析了薄膜的光学和电学性能并优化其沉积工艺后,研制出了一款背面光照转换效率为 7.1%的双面超薄太阳能电池,这是目前吸收层厚度不超过 1 微米的 CdTe 太阳能电池所达到的最佳背面光照效率。此外,通过运用 SCAPS 软件模拟设计,带有 ZnTe:N/IWO 复合透明背电极的双面超薄 CdTe 太阳能电池在背面光照下的最大理论效率可达 20%。
English Abstract
Fabrication of bifacial translucent solar cell is a promising technology for the development of building integrated photovoltaics and the construction of tandem solar cell. In this work, cadmium telluride (CdTe) polycrystalline thin films with a thickness of 1 μm were prepared by using close space sublimation system while nitrogen-doped zinc telluride (ZnTe: N) and tungsten-doped indium oxide (IWO) layers were deposited by using magnetron sputtering and reactive plasma deposition technology, respectively. After analyzing the optical and electrical properties of films and optimizing their deposition processes, a bifacial ultrathin solar cell with a 7.1% back illumination conversion efficiency was developed, which was currently the best back illumination efficiency for CdTe solar cell with an absorption layer thickness of no more than 1 μm. Furthermore, the bifacial ultrathin CdTe solar cell with ZnTe:N/IWO composite transparent back electrode can achieved a maximum theoretical efficiency of up to 20% under the back illumination by employing SCAP software simulation design.
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SunView 深度解读
该双面超薄CdTe电池技术对阳光电源建筑光伏一体化(BIPV)产品线具有重要参考价值。ZnTe:N/IWO复合透明背电极实现的双面发电与半透明特性,可启发SG系列组件级逆变器针对双面发电场景优化MPPT算法,提升背面光利用率。超薄轻质特性契合建筑幕墙、采光顶等BIPV应用需求,可结合iSolarCloud平台开发双面辐照监测与发电量预测模型。该复合电极的载流子收集优化思路,对阳光电源钙钛矿叠层电池研发及高效异质结组件配套逆变器设计具有借鉴意义,特别是在1500V高压系统中提升弱光响应性能。