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用于能量存储和多巴胺检测的电解质不同温度下TMS@CNTs纳米复合电极电化学杂化器件
Electrochemical hybrid devices for energy storage and dopamine detection using TMS@CNTs nanocomposite electrodes at different temperatures of electrolyte
| 作者 | Nimra Muzaffar · Amir Muhammad Afzal · Muhammad Waqas Iqbal |
| 期刊 | Journal of Materials Science: Materials in Electronics |
| 出版日期 | 2025年1月 |
| 卷/期 | 第 36.0 卷 |
| 技术分类 | 储能系统技术 |
| 技术标签 | 储能系统 GaN器件 |
| 相关度评分 | ★★★★★ 5.0 / 5.0 |
| 关键词 | 多巴胺 电化学检测 TMS@CNTs纳米复合材料 能量存储 生物电子器件 |
语言:
中文摘要
多巴胺是一种重要的脑部化学物质,属于儿茶酚胺类和苯乙胺类有机化合物,对健康幸福的生活至关重要。典型的多巴胺释放异常与多种神经系统疾病以及抑郁状态密切相关。因此,为了全面理解其生理功能,开展多巴胺(DA)水平的实时体内监测显得尤为必要。本文采用水热法合成了硫化钴铌(CoNbS)。所制备的复合电极材料(CoNbS/CNT)具有独特的纳米结构,为离子迁移提供了通道,从而实现了优异的电化学性能。该电极还在不同温度下进行了测试,以获得最佳参数值。在扫描速率为3 mV s⁻¹时,CoNbS/CNT的比容量(Qs)达到700 C g⁻¹,相较于未掺杂材料表现出更优越的性能。此外,成功构建了非对称超级电容器器件,在3 mV s⁻¹下实现了183.2 C g⁻¹的显著比容量,超过了以往报道的数值。该器件获得了高达75 Wh kg⁻¹的优异能量密度(Ed)和800 W kg⁻¹的显著功率密度(Pd)。同时,器件还实现了86%的出色库仑效率(CE)。另外,该传感器在人血清中对多巴胺(DA)的检测响应可靠,回收率稳定保持在101.8%至103.2%的精确范围内。这种多功能CoNbS/CNT纳米复合电极材料为设计用于能量收集和生物医学应用的杂化器件开辟了新的前景。
English Abstract
Dopamine, an imperative brain chemical belong to an organic chemical of the catecholamine and phenethylamine families, is essential for a healthy and happy life. The occurrence of a typical dopamine release is associated with several neurological disorders as well as depressive conditions. Hence, it is essential to conduct real-time in vivo monitoring of DA levels in order to comprehend its physiological functions comprehensively. Herein, the hydrothermal procedure is employed for the preparation of cobalt niobium sulfide (CoNbS). The unique nanostructure of the composite electrode material (CoNbS/CNT) fabricated in this work offers channels for ion mobilization and leads to exceptional electrochemical parameters. The electrode is also measured at different temperatures to get the optimum values. The specific capacity (Qs) of the CoNbS/CNT is calculated 700 Cg −1 at 3 mVs −1 , which is comparatively superior to the undoped material. Furthermore, the asymmetric supercapacitor device is successfully fabricated, attaining a remarkable Qs of 183.2 Cg −1 at 3 mVs −1 , surpassing previously recorded values. The gadget yielded an exceptional energy density ( E d ) of 75 Whkg⁻ 1 and a notable power density ( P d ) of 800 Wkg⁻ 1 . Moreover, the device achieved an outstanding columbic efficiency (CE) of 86%. Additionally, the sensor reliably delivers responses for dopamine (DA) in human serum, sustaining an accurate range of 101.8% to 103.2%. The multifunctional CoNbS/CNT nanocomposite electrode material presents novel prospects for the design of hybrid devices in energy harvesting and biomedical applications.
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SunView 深度解读
该CoNbS/CNT纳米复合电极技术对阳光电源储能系统具有重要参考价值。其700 Cg⁻¹比容量和86%库仑效率可启发ST系列PCS的电极材料优化,提升PowerTitan储能系统的能量密度(75 Whkg⁻¹)和功率密度(800 Wkg⁻¹)。不同温度下的电化学性能测试为储能设备宽温域运行提供数据支撑。该混合器件的多功能特性可拓展至EV充电桩的储能单元设计,并为iSolarCloud平台的电池健康监测算法提供电化学传感新思路,推动储能系统智能化运维技术升级。