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光伏发电技术 GaN器件 ★ 5.0

Er3+掺杂NaSrVO4无机荧光粉的上转换发光及Judd-Ofelt分析

Upconversion luminescence and Judd–Ofelt analysis of Er3+ doped NaSrVO4 inorganic phosphor

作者 Meniak Khajuria · Sajad A. Bhat · Rohit Raina
期刊 Journal of Materials Science: Materials in Electronics
出版日期 2025年1月
卷/期 第 36.0 卷
技术分类 光伏发电技术
技术标签 GaN器件
相关度评分 ★★★★★ 5.0 / 5.0
关键词 上转换发光 Er³⁺激活 NaSrVO₄荧光粉 燃烧法 Judd-Ofelt理论
语言:

中文摘要

含有上转换发光材料的纳米荧光粉的发展已显示出其在光伏领域中的潜在应用。在此背景下,本文研究了Er3+离子激活的NaSrVO4荧光粉的上转换发光性能。采用以尿素为燃料的简便燃烧法制备了NaSr(1-x)VO4:xEr3+(0.01 ≤ x ≤ 0.04)系列荧光粉。通过粉末X射线衍射对样品相纯度进行分析,结果表明所制备的材料为单相结构,属于单斜晶系P21/n空间群。利用透射电子显微镜和X射线光电子能谱对荧光粉的形貌特征及元素组成进行了表征。结果表明,掺杂元素铒以+3价态存在。掺杂样品的直接带隙为3.69 eV。系统研究了上转换光致发光特性,并深入分析了掺杂剂(Er3+)浓度对发光性能的影响。所制备荧光粉的发射光位于光谱的绿色区域,且具有良好的色纯度。总体而言,研究结果表明该合成荧光粉在光电子材料领域具有潜在应用前景。

English Abstract

The development of nano-phosphors containing upconverting luminescent materials has demonstrated their potential applications in photovoltaics. In this context, this article explores the upconversion capabilities of NaSrVO 4 phosphor when activated by Er 3+ ions. The NaSr (1- x ) VO 4 : x Er 3+ (0.01 ≤ x ≤ 0.04) phosphors were synthesized using a facile combustion method with urea as the fuel. Phase purity, investigated through powder X-ray diffraction, confirms the formation of a single-phase (monoclinic) material with a P2 1/n space group. The morphological and elemental composition of the phosphor were analyzed using transmission electron microscopy and X-ray photoelectron spectroscopy. The dopant, erbium, was found to be in the + 3 oxidation state. The direct bandgap of the synthesized phosphor is 3.69 eV for the doped sample. Upconversion photoluminescence was systematically studied, and the impact of dopant (Er 3+ ) concentration on luminescent properties was extensively analyzed. The emission color of the synthesized phosphor falls within the green region of the spectrum and exhibits good color purity. Overall, the results suggest the potential application of the synthesized phosphor in the field of optoelectronic materials.
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SunView 深度解读

该Er³⁺掺杂上转换发光材料研究对阳光电源光伏系统具有潜在价值。上转换磷光体可将近红外光转换为可见光,提升SG系列组串/集中式逆变器的光谱响应范围,突破硅基电池的光谱利用瓶颈。其3.69eV带隙特性与GaN功率器件的宽禁带特性协同,可为阳光电源新一代1500V高压系统的GaN逆变拓扑提供光电转换效率优化思路,同时该纳米磷光体技术可集成于iSolarCloud平台的智能组件监测,通过光谱分析实现电站性能诊断,为提升系统发电量提供新路径。