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储能系统技术 储能系统 GaN器件 ★ 5.0

用于提升超级电容器效率和析氢反应的高性能Co-MOF@WS₂电极

High-performance Co-MOF@WS₂ electrode for enhanced supercapacitor efficiency and hydrogen evolution reaction

作者 Qaisar Mehmood Ali
期刊 Journal of Materials Science: Materials in Electronics
出版日期 2025年1月
卷/期 第 36.0 卷
技术分类 储能系统技术
技术标签 储能系统 GaN器件
相关度评分 ★★★★★ 5.0 / 5.0
关键词 杂化纳米结构 超级电容器 Co-MOF@WS₂复合材料 电荷存储能力 析氢反应
语言:

中文摘要

开发先进的杂化纳米结构对于提升下一代储能器件的电化学性能至关重要。本研究报道了一种在泡沫镍上生长的具有分级结构的Co-MOF@WS₂复合材料的制备方法,该材料旨在用于高性能超级电容器应用。本文提出了一种以泡沫镍为基底、具有分级结构的Co-MOF@WS₂复合材料作为超级电容器的电极材料,表现出优异的电化学性能。研究表明,Co-MOF@WS₂材料在1 M KOH溶液中于2 A/g电流密度下实现了高达2901 C/g的比电容,超过了此前报道的各类MOF基材料的电容性能。以Co-MOF@WS₂作为正极,活性炭(AC)作为负极构建的非对称超级电容器(ASC)器件,在功率密度为1008 W/kg时达到了80.1 Wh/kg的高能量密度,并且在经历12,000次循环后仍保持了83.6%的电容保留率。

English Abstract

The development of advanced hybrid nanostructures is essential for improving the electrochemical performance of next-generation energy storage devices. In this study, we report the fabrication of a hierarchically organized Co-MOF@WS 2 composite grown on nickel foam, designed for high-performance supercapacitor applications. The present study presents a hierarchically organized Co-MOF@WS 2 supported on nickel foam as an electrode material with exceptional performance for supercapacitors. This study demonstrates that the Co-MOF@WS 2 material achieves an exceptionally high specific capacitance of 2901 C/g at 2 A/g in a 1 M KOH solution, surpassing the capacitances of previously documented MOF-based materials. Co-MOF@WS 2 is employed as the positive electrode and activated carbon (AC) serves as the negative electrode, an asymmetric supercapacitor (ASC) device attains a high energy density of 80.1 Wh/kg at a power density of 1008 W/kg, with a capacitance retention of 83.6% after 12,000 cycles.
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SunView 深度解读

该Co-MOF@WS₂复合电极技术对阳光电源储能系统具有重要参考价值。其2901 C/g的超高比电容和80.1 Wh/kg能量密度,为ST系列PCS和PowerTitan储能系统的电化学储能单元优化提供新思路。该材料在12000次循环后仍保持83.6%容量保持率,可提升储能系统全生命周期性能。同时,其氢析出反应特性与阳光电源氢能业务布局形成协同,可应用于电解水制氢系统的电极材料研发,推动光储氢一体化解决方案的技术升级。