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可靠性与测试
★ 5.0
废弃粉煤灰/高岭土复合材料介电与铁电性能的探索
Exploration of dielectric and ferroelectric properties of waste fly ash/kaolin composite: synergistic effect on impedance and polarizability
| 作者 | Muktikanta Panigrahi |
| 期刊 | Journal of Materials Science: Materials in Electronics |
| 出版日期 | 2025年1月 |
| 卷/期 | 第 36.0 卷 |
| 技术分类 | 可靠性与测试 |
| 相关度评分 | ★★★★★ 5.0 / 5.0 |
| 关键词 | 粉煤灰 复合材料 介电性能 铁电性能 资源化利用 |
语言:
中文摘要
在复合体系中以粉煤灰为基体,可提供一种比传统陶瓷(尤其是瓷器类陶瓷产品)成本更低的替代方案。粉煤灰通常来源于火力发电厂,常被视为废弃物,是煤炭燃烧的副产物,对环境构成威胁。本研究旨在将电厂产生的粉煤灰废料用于电子领域应用,从而产生显著的社会经济效益。本文开发了一种利用粉煤灰与高岭土制备的介电材料。通过原料烧结,该材料在室温下表现出改善的电学和介电性能。复合材料的阻抗从28.51 MΩ显著提升至40.50 MΩ。X射线衍射分析揭示了材料中存在的多种物相。扫描电子显微图像显示复合材料具有致密的结构以及粉煤灰的球形形貌。原子力显微镜被用于探究样品的三维表面形貌。拉曼光谱分析表明所制备的复合材料中存在非晶态莫来石相。铁电P-E回线测量结果显示,与纯粉煤灰(7.85 nC/cm²)相比,复合材料的饱和极化强度得到增强,达到10.70 nC/cm²。综合微观结构、电学、介电及铁电性能分析表明,所开发的轻质复合材料有望作为昂贵陶瓷材料的替代品。
English Abstract
Using fly ash as a matrix in a composite system offers a low-cost alternative to costlier ceramics, particularly porcelain ceramic products. Fly ash is usually obtained from thermal power plants and is mostly termed waste. It is produced by the combustion of coal, which endangers our environment. The objective of the present study is to utilize the fly ash waste from the power plants for electronic applications, which will have a significant socio-economic impact. A dielectric material has been developed utilizing fly ash and kaolin. Improved electrical and dielectric properties of the material at room temperature result from the sintering of raw ingredients. The impedance of the composite significantly enhanced from 28.51 to 40.50 MΩ. The X-ray diffraction analysis shows the various phases present in the material. Scanning electron micrographs reveal a compact structure of the composite and spherical morphology of the fly ash. Atomic force microscopy is implemented to explore the 3-dimensional profile of the samples. The Raman spectrum analysis revealed the presence of an amorphous mullite phase in the prepared composite. The ferroelectric P-E loop measurement shows enhanced saturation polarization for the composite material (10.70 nC/cm 2 ) compared to the fly ash (7.85 nC/cm 2 ). The microstructural, electrical, dielectric, and ferroelectric properties indicate that the developed lightweight composites may be used as a replacement for costlier ceramic materials.
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SunView 深度解读
该粉煤灰/高岭土复合介电材料研究对阳光电源储能系统具有重要参考价值。材料阻抗提升至40.50MΩ及饱和极化强度达10.70nC/cm²,可应用于ST系列PCS的电容器介质层和PowerTitan储能系统的绝缘结构优化。利用电厂废弃粉煤灰替代昂贵陶瓷材料,符合阳光电源绿色制造理念,可降低储能变流器和充电桩产品的介电材料成本,同时提升设备可靠性。其铁电特性可为SiC/GaN功率器件的栅极介质层改进提供新思路,助力三电平拓扑结构的绝缘性能提升。