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氮化硅钝化层在多晶硅表面织构化及其功能行为研究
Texturing of silicon nitride passivation layers on functional behaviour study of polycrystalline silicon (p-Si) made with plasma enhanced chemical vapour deposition
| 作者 | Springer Nature remains neutral with regard to jurisdictional claims in published maps · institutional affiliations. |
| 期刊 | Journal of Materials Science: Materials in Electronics |
| 出版日期 | 2025年1月 |
| 卷/期 | 第 36.0 卷 |
| 技术分类 | 光伏发电技术 |
| 技术标签 | 储能系统 |
| 相关度评分 | ★★★★★ 5.0 / 5.0 |
| 关键词 | 多晶硅 氮化硅 PECVD 钝化层 光吸收 |
语言:
中文摘要
多晶硅(p-Si)因其成本效益高、在太阳能电池中的高效性以及在电子器件中的广泛应用,对半导体和光伏产业至关重要。本研究通过等离子体增强化学气相沉积(PECVD)方法制备了具有不同厚度氮化硅(SiNx)涂层的多晶硅(p-Si)层,并系统合成与评估了其功能性特征。该研究探讨了不同厚度的SiNx织构层对底层p-Si基底光学和电子特性的影响。结果证实,SiNx钝化层对于提升基于p-Si器件的效率具有关键作用,能够降低表面复合速率、提高太阳能转换效率并增强光捕获能力。本文还研究了SiNx涂层厚度对p-Si材料结构、光学及电学行为的影响。实验表明,具有30 nm厚SiNx层的p-Si样品表现出良好的透射率(65%)、优化的带隙(1.55 eV)、更优的I-V性能、最佳吸收电流(1.6 × 10⁻⁴ mA/cm²)以及更高的量子效率(86%),适用于太阳能电池器件的制备。
English Abstract
Polycrystalline silicon (p-Si) is essential for semiconductor and photovoltaic industries due to its cost-effectiveness, efficiency in solar cells, and versatile applications in electronics. This research investigation synthesized and evaluated the functional characteristics of polycrystalline silicon (p-Si) layer featuring varied thicknesses of silicon nitride (SiNx) coating via plasma enhanced chemical vapour deposition (PECVD). This study explores how SiNx texturing layers with various thicknesses affect the optical and electronic properties of the underlying p-Si substrate. It confirms that SiNx passivation layers are crucial in improving the efficiency of p-Si-based devices by reducing surface recombination velocities, improving solar efficiency, and enhancing light trapping. The effect of SiNx coating thickness on the structural, optical, and electrical behaviour of p-Si is studied. The p-Si featured with 30 nm is good transmittance (65%), improved band gap (1.55 eV), better I-V performance, optimum absorption current (1.6 X 10 –4 mA/cm 2 ), and improved quantum efficiency (86%), which is suitable making solar cell applications.
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SunView 深度解读
该p-Si/SiNx钝化层研究对阳光电源SG系列光伏逆变器及PowerTitan储能系统具有重要价值。30nm SiNx层实现86%量子效率和1.55eV带隙优化,可提升组件端转换效率,直接增强MPPT算法输入功率质量。降低表面复合速率技术可应用于1500V高压系统的组件选型标准,优化iSolarCloud平台的发电量预测模型。该钝化工艺对提升储能系统PCS的直流侧兼容性和全生命周期发电效率具有指导意义,支撑阳光电源光储一体化解决方案的系统级效率优化。