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通过SILAR法制备片状-棒状SrO薄膜用于超级电容器高效能量存储
Development of flake-rod like SrO thin films via SILAR method for efficient energy storage in supercapacitors
| 作者 | The SrO thin films electrode was successfully synthesized using the Successive Ionic Layer Adsorption · Reaction (SILAR) technique |
| 期刊 | Journal of Materials Science: Materials in Electronics |
| 出版日期 | 2025年1月 |
| 卷/期 | 第 36.0 卷 |
| 技术分类 | 储能系统技术 |
| 技术标签 | 储能系统 |
| 相关度评分 | ★★★★★ 5.0 / 5.0 |
| 关键词 | SrO薄膜 SILAR技术 立方晶相 比电容 循环稳定性 |
语言:
中文摘要
采用连续离子层吸附与反应(SILAR)技术成功合成了SrO薄膜电极,XRD分析表明其具有明确的立方晶相结构,平均晶粒尺寸为18 nm。该薄膜呈现出片状-棒状的微观形貌,提供了较大的比表面积,并促进了离子的高效扩散,从而显著提升了其电化学性能。电化学测试结果显示,在扫描速率为5 mV/s时,其比电容(Cs (cv))达到599.5 F/g,同时表现出优异的循环稳定性,在经历6000次循环后仍保持初始电容的83.4%。此外,Ragone图分析表明该材料在能量密度与功率密度之间实现了良好的平衡,凸显了SrO薄膜电极作为高性能超级电容器候选材料的巨大潜力。
English Abstract
The SrO thin films electrode was successfully synthesized using the Successive Ionic Layer Adsorption and Reaction (SILAR) technique, exhibiting a well-defined cubic crystalline structure with an average crystallite size of 18 nm, as confirmed through XRD analysis. The films demonstrated a flake-rod like morphology, which provided a high surface area and facilitated efficient ion diffusion, thereby enhancing their electrochemical performance. Electrochemical measurements revealed a specific capacitance ( Cs (cv) ) of 599.5 F/g at a sweep rate of 5 mV/s, coupled with outstanding cycling stability, retentive 83.4% of an initial capacitance after 6000 cycles. Additionally, the Ragone plot analysis indicated a good balance between energy density as well power density, underscoring a potential of SrO thin films electrode as a promising material for higher performance supercapacitors.
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SunView 深度解读
该SrO薄膜超级电容器技术对阳光电源储能系统具有重要参考价值。其599.5 F/g比电容和83.4%循环稳定性(6000次)可为ST系列PCS的直流侧储能单元提供快速功率缓冲方案,特别适用于PowerTitan系统的调频调峰场景。SILAR制备工艺的低成本特性与公司储能产品降本路线契合,flake-rod形貌带来的高比表面积设计思路可启发电池包热管理优化。建议在混合储能系统中探索超级电容与锂电池协同配置,提升iSolarCloud平台管理的储能电站动态响应能力。