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光伏发电技术 储能系统 ★ 5.0

不同PANI:Rubrene界面混合比例下光照对Al/p-Si肖特基二极管光伏特性影响的研究

Investigation of illumination effects on photovoltaic features of Al/p-Si Schottky diode with different amount of mixed PANI: Rubrene interface

作者 In Fig. 6 a–d
期刊 Journal of Materials Science: Materials in Electronics
出版日期 2025年1月
卷/期 第 36.0 卷
技术分类 光伏发电技术
技术标签 储能系统
相关度评分 ★★★★★ 5.0 / 5.0
关键词 Al/PANI:Rubrene/p-Si 肖特基光电二极管 光电响应 界面层材料 光照条件
语言:

中文摘要

在本研究中,制备了Al/PANI:Rubrene/p-Si肖特基光电二极管。为实现该过程,将不同量的Rubrene添加到PANI中,并作为器件中的界面材料使用。为了评估所制备器件的电学性能,根据添加剂含量的不同,在暗态及不同光照强度(从20至100 mW/cm²,间隔为20 mW/cm²)下进行了多种光电响应测量。对测量结果进行了分析,并计算了一些性能参数,如理想因子(n)、势垒高度(ΦB)、饱和电流(Io)和串联电阻(Rs)。对于混合比例为1:0.5的二极管,随着光照强度的增加,其光电流最高值介于4.46 × 10⁻² A与6.50 × 10⁻² A之间。在100 mW/cm²光照强度下,测得响应度和灵敏度分别为4.97 A/W和10.44。在20 mW/cm²光照强度下,比例为1:0.5的器件的最大探测率达到了6.25 × 10¹⁰ Jones。这些测量结果表明,所有器件均对光具有敏感性,且二极管的光敏特性随混合比例的不同而变化。根据所获得的数据结果可以看出,这些器件表现出明显的光伏特性,可用于光电子器件应用。

English Abstract

In this study, Al/PANI: Rubrene/p-Si Schottky photodiodes were produced. To perform this process, different amounts of Rubrene were added to the PANI and used as an interfacial material in device. In order to evaluate the electrical properties of produced device, various photo-response measurements, were made in dark and at illumination intensities (from 20 to 100 mW/cm 2 with 20 mW/cm 2 intervals) depending on amount of additives. The measurement results were analyzed and some performance parameters such as ideality factor ( n ), barrier height ( Φ B ), saturation current ( I o ), and series resistance ( R s ) were calculated. The highest photocurrent values were obtained between 4.46 × 10 –2 A and 6.50 × 10 –2 A depending on increasing light intensity for diode with a ratio of 1:0.5. Responsivity and sensitivity have been found to be 4.97 A/W and 10.44, respectively, at 100 mW/cm 2 . Maximum detectivity has found 6.25 × 10 10 Jones at 20 mW/cm 2 light intensity for device at 1:0.5 ratio. These measurements showed that all devices were sensitive to the light. In addition, the light sensitivity of diodes varies depending on the amount of mixing. As a result of data obtained, it was seen that devices demonstrated photovoltaic properties and were found to be usable for optoelectronic applications.
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SunView 深度解读

该肖特基光电二极管研究对阳光电源SG系列光伏逆变器的MPPT优化具有参考价值。PANI:Rubrene混合界面材料在不同光照强度下的光响应特性(20-100mW/cm²)可为逆变器光照传感器设计提供思路,最优1:0.5配比实现的高探测率(6.25×10¹⁰ Jones)和响应度(4.97 A/W)表明有机半导体界面工程可提升光伏系统弱光响应性能。该技术可应用于iSolarCloud平台的光照监测模块,优化1500V系统在复杂光照条件下的发电效率预测和智能运维算法。