← 返回
光伏发电技术 储能系统 ★ 5.0

利用新型TiO₂-WO₃-GO纳米结构光阳极提升染料敏化太阳能电池的光电性能

Enhancing photovoltaic performance of DSSCs using novel TiO2-WO3-GO nanostructured photoanodes

作者 Springer Nature remains neutral with regard to jurisdictional claims in published maps · institutional affiliations.
期刊 Journal of Materials Science: Materials in Electronics
出版日期 2025年1月
卷/期 第 36.0 卷
技术分类 光伏发电技术
技术标签 储能系统
相关度评分 ★★★★★ 5.0 / 5.0
关键词 TiO2-WO3-石墨烯氧化物 水热法 光阳极 光电转换效率 电荷复合
语言:

中文摘要

本研究报道了一种新型三元TiO₂-WO₃-GO纳米复合材料的合成及其作为光阳极材料在提高染料敏化太阳能电池(DSSCs)效率中的应用。该复合材料通过简单的水热法制备,并采用能量色散X射线光谱(EDS)、透射电子显微镜(TEM)和扫描电子显微镜(SEM)进行表征,结果均证实了TiO₂、WO₃和氧化石墨烯(GO)的成功复合。此外,还利用X射线衍射(XRD)和傅里叶变换红外光谱(FTIR)进一步确认了GO和WO₃组分的形成。为了提升DSSC的性能,研究探讨了不同GO浓度(0.01–0.03 g)对电荷转移和光吸收特性的影响。研究结果表明,引入GO可增强光吸收能力,而WO₃则有助于减少电子-空穴复合,并促进纳米复合材料内部高效的电子传输。当GO浓度为0.025 g时,光阳极性能达到最优,所制备的DSSC表现出显著提升的短路电流密度(15.3 mA/cm²)、开路电压(0.763 V)、填充因子(0.68)以及功率转换效率(8.3%)。这些性能的提升表明,与仅基于TiO₂或TiO₂-WO₃的光阳极相比,TiO₂-WO₃-GO光阳极具有更优异的光电性能。

English Abstract

This study presents the synthesis and application of a novel ternary TiO 2 -WO 3 -GO nanocomposite as a photoanode material to improve the efficiency of dye-sensitized solar cells (DSSCs). The composite was prepared via a simple hydrothermal approach and analyzed using energy-dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and scanning electron microscopy (SEM), all of which verified the successful integration of TiO 2 , WO 3 , and graphene oxide (GO). Additionally, X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR) were employed to confirm the formation of the GO and WO₃ components. To enhance DSSC performance, the influence of different GO concentrations (0.01–0.03 g) on charge transfer and light absorption properties was explored. The findings revealed that the inclusion of GO improved light absorption, while WO 3 reduced electron–hole recombination and facilitated efficient electron transfer within the nanocomposite. The optimal photoanode performance was observed at a GO concentration of 0.025 g, which resulted in a DSSC with a significant enhancement in short-circuit current density (15.3 mA/cm 2 ), open-circuit voltage (0.763 V), fill factor (0.68), and power conversion efficiency (8.3%). These improvements demonstrate the superior performance of TiO 2 -WO 3 -GO photoanodes compared to those solely based on TiO 2 or TiO 2 -WO 3 .
S

SunView 深度解读

该TiO2-WO3-GO三元纳米复合光阳极技术对阳光电源SG系列光伏逆变器具有重要参考价值。研究中8.3%的DSSC效率提升和15.3mA/cm²的短路电流密度改善,验证了纳米材料优化电荷传输的有效性。其抑制电子-空穴复合的机制可启发我们在SiC/GaN功率器件界面优化和MPPT算法改进方向的研究,特别是在弱光响应和温度稳定性方面。该材料体系的光吸收增强原理可应用于iSolarCloud平台的组件性能预测模型,为分布式光伏系统效率提升提供理论支撑。