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光伏发电技术 ★ 5.0

用于光伏应用的热蒸发SnSe纳米结构层的研究

Investigation of thermally evaporated SnSe nano structure layer for photovoltaic use: a structural, morphological, and electrical analysis

作者 Raja Krishnamoorthy
期刊 Journal of Materials Science: Materials in Electronics
出版日期 2025年1月
卷/期 第 36.0 卷
技术分类 光伏发电技术
相关度评分 ★★★★★ 5.0 / 5.0
关键词 SnSe 热蒸镀法 光伏器件 结晶性 电导特性
语言:

中文摘要

采用纳米结构光伏技术的太阳能组件每瓦发电成本经济实惠,是建筑集成光伏应用和大规模太阳能电站的理想选择。本研究利用热蒸镀法在玻璃和氧化铝衬底上制备了正交晶系的硒化亚锡(SnSe)纳米结构,并系统分析了其在光伏应用中的特性。通过X射线衍射(XRD)、扫描电子显微镜(SEM)和原子力显微镜(AFM)分别对所沉积纳米结构的形貌和结构特征进行了系统分析与表征。同时,还考察了衬底温度以及衬底材料类型对氧化铝和玻璃衬底上各类纳米结构特性的影响。XRD分析表明,随着温度变化会出现混合相结构。能谱分析(EDS)显示在高温条件下存在氧元素,并证实所有目标元素均已存在。原子力显微镜(AFM)图像被用于分析所生成纳米结构的表面形貌。获得的物相及硒的蒸发温度对光学性能研究具有显著影响。此外,还进一步研究了氧化铝衬底上纳米结构的光伏特性。

English Abstract

Solar modules with nanostructures photovoltaic technology generate power at an economical cost per watt. They are ideal options for both building-integrated photovoltaic applications and large-scale solar farms. In this work, thermal vapour deposition has been employed to create orthorhombic tin selenide nanostructures on glass and alumina substrates to analyze its characteristics for photovoltaic applications. The morphological, structural characterization for the deposited nanostructures were methodically analyzed and examined using XRD, SEM, and AFM, respectively. Further the influence of the substrate temperature and substrate material type on diverse nanostructure characteristics onto alumina and glass substrates were also examined. A mixed phase appears as a function of temperature, according to XRD analysis. Electron dispersive spectroscopy (EDS) reveals the presence of oxygen at high temperatures and confirm that all the required elements are present. Atomic force microscopy (AFM) images were utilized for analyzing the surface topography of the generated nanostructures. The acquired phase and the selenium temperature had a notable impact on optical studies. The photovoltaic characteristics of the nanostructures over alumina substrates were also investigated.
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SunView 深度解读

该SnSe纳米结构光伏材料研究对阳光电源SG系列逆变器及组件集成具有前瞻价值。热蒸发法制备的正交晶系SnSe薄膜展现出温度依赖的混合相特性,其光电转换效率优化可为新型光伏组件开发提供材料选择方向。纳米结构的形貌调控与基底温度关联性研究,可指导我司1500V高压系统中组件端的光电特性匹配优化。该低成本纳米光伏技术若实现产业化,将推动BIPV应用场景下SG逆变器的MPPT算法针对新型薄膜组件的自适应优化,提升系统整体发电效率与经济性。