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储能系统技术 储能系统 ★ 5.0

Bi2O2Se纳米片在光电化学系统中的可逆变色行为

Reversible discoloration behavior of Bi2O2Se nanosheets in photoelectrochemical systems

作者 Silan Zhou · Nanyin Zhao
期刊 Journal of Materials Science: Materials in Electronics
出版日期 2025年2月
卷/期 第 36.0 卷
技术分类 储能系统技术
技术标签 储能系统
相关度评分 ★★★★★ 5.0 / 5.0
关键词 电致变色 电化学储能 Bi2O2Se 水热法 光学对比度
语言:

中文摘要

电致变色材料是一类在电场作用下发生电子和离子嵌入或脱出的物质,该过程本质上是氧化还原反应。这些材料能够从一种颜色转变为另一种颜色,并在施加反向电压后表现出可逆的颜色变化。在本研究中,我们报道了一种新型材料Bi2O2Se,其兼具电致变色和电化学储能功能。我们采用水热法成功合成了Bi2O2Se纳米片,并在电化学工作站上利用三电极系统对其进行了电化学测试。在外加电场作用下,Bi2O2Se纳米片由灰色转变为黄色。该变色行为在施加反向电压后可逆,从而表现出电致变色效应。变色后在0 V电压下放电,产生反向电流。在此放电过程中,Bi2O2Se电极的颜色逐渐恢复,展现出其储能能力。上述结果表明,Bi2O2Se纳米片在集成电致变色功能与储能能力的应用方面具有广阔前景。在不久的将来,这类材料有望对我们的日常生活产生重要影响。

English Abstract

Electrochromic materials are substances that undergo the implantation or removal of electrons and ions in response to an electric field, which is redox reactions. These materials can change from one color to another and exhibit a reversible color change after a reverse voltage is applied. In this study, we report a novel material, Bi 2 O 2 Se, capable of both electrochromic and electrochemical energy storage. We successfully synthesized Bi 2 O 2 Se nanosheets using a hydrothermal method. Electrochemical tests on the Bi 2 O 2 Se nanosheets were conducted utilizing a three-electrode system at an electrochemical workstation. Under the influence of an electric field, the Bi 2 O 2 Se nanosheets transitioned from gray to yellow. This discoloration behavior was reversible upon applying reverse voltage, thereby exhibiting an electrochromic effect. Discharge at a voltage of 0 V after discoloration, resulting in reverse current generation. During this discharge process, the color of the Bi 2 O 2 Se electrode gradually recovers, exhibiting its energy storage capability. These findings suggest that Bi 2 O 2 Se nanosheets hold promise for potential applications that integrate both electrochromic functionality and energy storage capabilities. In the near future, they are likely to have a substantial impact on our daily lives.
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SunView 深度解读

该Bi2O2Se纳米片的电致变色与储能双功能特性对阳光电源储能系统具有创新启发价值。其可逆氧化还原机制可为ST系列PCS的电极材料优化提供新思路,特别是在能量存储过程中的电子-离子协同传输机制。该材料的变色特性可应用于PowerTitan储能柜的可视化状态监测,通过颜色变化直观反映充放电状态,配合iSolarCloud平台实现智能运维。其快速响应的电化学特性对提升储能系统功率密度和循环寿命具有参考意义,可探索应用于三电极体系的能量管理优化。