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水性电解质对WS2纳米片电化学性能影响的研究
An investigation on the effect of aqueous electrolytes on the electrochemical performance of WS2 nanosheets
| 作者 | Visakh V. Mohan |
| 期刊 | Journal of Materials Science: Materials in Electronics |
| 出版日期 | 2025年1月 |
| 卷/期 | 第 36.0 卷 |
| 技术分类 | 储能系统技术 |
| 技术标签 | 储能系统 |
| 相关度评分 | ★★★★★ 5.0 / 5.0 |
| 关键词 | 超级电容器 二维WS2纳米片 电解质性质 电化学储能 对称结构 |
语言:
中文摘要
为了提高超级电容器的能量密度、功率密度和循环稳定性,必须深入理解并有效调控电极与电解质之间的相互作用。评估电解质的性质对于确保超级电容器最佳性能具有至关重要的作用。在本研究中,评估了基于二维WS2纳米片的对称超级电容器在碱性(1 M KOH)、酸性(1 M H2SO4)和中性(1 M Na2SO4)电解质中的电化学储能性能。在1 A g−1的恒定比电流下,该超级电容器在KOH、H2SO4和Na2SO4电解质中分别表现出170、108和89 F g−1的比电容值。在0.8 kW kg−1的功率密度下,相应的能量密度值分别为15、9.6和8 Wh kg−1,分别对应于碱性、酸性和中性电解质。WS2纳米片在KOH电解质中表现出优异的性能,在10,000次连续充放电循环后仍能保持初始电容值的100%。
English Abstract
To enhance the energy density, power density, and cycling stability of supercapacitors, it is imperative to comprehend and control the interplay between electrodes and the electrolyte. Assessment of electrolyte properties plays a crucial role in guaranteeing the best performance of supercapacitors. In this study, electrochemical energy storage performance of symmetric supercapacitors based on 2D WS 2 nanosheets has been evaluated in alkaline (1 M KOH), acidic (1 M H 2 SO 4 ), and neutral (1 M Na 2 SO 4 ) electrolytes. At a constant specific current of 1A g −1 , the supercapcitors exhibit specific capacitance values of 170, 108, and 89 F g −1 , respectively in KOH, H 2 SO 4 , and Na 2 SO 4 electrolytes. At a power density of 0.8 kW kg −1 , the associated energy density values are calculated as 15, 9.6, and 8 Wh kg −1 for alkaline, acidic, and neutral electrolytes, respectively. WS 2 nanosheets deliver superior performance in KOH electrolyte by retaining the 100% of the initial capacitance value even after 10,000 continuous charge–discharge cycles.
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SunView 深度解读
该WS2纳米片超级电容器研究对阳光电源储能系统具有重要参考价值。研究表明碱性电解质(KOH)可实现170 F/g比电容和15 Wh/kg能量密度,且10000次循环后容量保持率100%,为ST系列PCS和PowerTitan储能系统的混合储能架构提供了超长寿命功率缓冲方案。该技术可应用于充电桩的峰值功率补偿单元,改善电网冲击;亦可集成至iSolarCloud平台的储能健康管理算法,通过电解质优化延长系统寿命,降低LCOS成本。