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储能系统技术
★ 5.0
用于高性能非对称超级电容器器件应用的ZrO2@MoO3负极材料
ZrO2@MoO3 anode for high performance asymmetric supercapacitor device application
| 作者 | Ashwani Maurya · Divya Singh |
| 期刊 | Journal of Materials Science: Materials in Electronics |
| 出版日期 | 2025年1月 |
| 卷/期 | 第 36.0 卷 |
| 技术分类 | 储能系统技术 |
| 相关度评分 | ★★★★★ 5.0 / 5.0 |
| 关键词 | ZrO2@MoO3 水热法 电化学性能 比电容 循环稳定性 |
语言:
中文摘要
开发稳定、高效且低成本的储能器件需要高性能的负极材料。ZrO2是一种稳定的电极材料,但其电化学性能较差。因此,在本研究中,我们采用水热法合成了ZrO2@MoO3作为负极材料,并研究了其电化学行为。ZrO2@MoO3的比电容在3.3 A/g电流密度下达到916 F/g。该电极在经过2000次循环后仍能保持其初始比电容的90%。为了验证ZrO2@MoO3作为负极材料的实际应用潜力,我们以活性炭(AC)为正极构建了非对称器件(ZrO2@MoO3//AC)。该器件的能量密度和功率密度分别为15 Wh/kg和933 W/kg。在充电30秒后,ZrO2@MoO3//AC器件能够点亮两个发光二极管(LEDs)并持续工作6分钟。
English Abstract
High performance anode materials are required for the development of stable, efficient and low cost energy storage devices. ZrO 2 is a stable electrode material. However, its electrochemical performance is poor. Thus, in the present study we have synthesized ZrO 2 @MoO 3 as an anode material using hydrothermal method and studied its electrochemical behaviour. The specific capacitance (SC) of the ZrO 2 @MoO 3 turns out to be 916 F/g at 3.3 A/g. The electrode retains 90% of its initial SC after 2000 cycles. To test the real life application of the ZrO 2 @MoO 3 as an anode material, asymmetric device was assembled using activated carbon (AC) as a cathode (ZrO 2 @MoO 3 //AC). The energy density and power density of ZrO 2 @MoO 3 //AC turns out to be 15 Wh/kg and 933 W/Kg, respectively. After 30 s of charging, ZrO 2 @MoO 3 //AC is used to light up two light emitting diodes (LEDs) for 6 mins.
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SunView 深度解读
该ZrO2@MoO3复合阳极材料展现出916 F/g比电容和15 Wh/kg能量密度,对阳光电源ST系列储能变流器和PowerTitan系统具有参考价值。其90%循环稳定性(2000次)和快速充放电特性可启发电化学储能单元优化,特别是在削峰填谷和频率调节场景。该材料的低成本制备路径为大规模储能系统降本提供思路,可与现有PCS拓扑协同,提升系统级能量密度和响应速度,增强电网侧储能竞争力。