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储能系统技术 ★ 5.0

Mg0.85Bi0.1ZrO3掺杂(Bi0.5Na0.5)0.7Sr0.3TiO3陶瓷的能量存储性能

Energy storage performance for Mg0.85Bi0.1ZrO3 doping (Bi0.5Na0.5)0.7Sr0.3TiO3 ceramics

作者 Xujun Li · Zhonghua Dai · Yuanyuan Zheng · Chenxi Liu
期刊 Journal of Materials Science: Materials in Electronics
出版日期 2025年1月
卷/期 第 36.0 卷
技术分类 储能系统技术
相关度评分 ★★★★★ 5.0 / 5.0
关键词 脉冲功率电容器 MBZ改性 BNST陶瓷 能量密度 击穿电场强度
语言:

中文摘要

近年来,随着电子元器件行业的快速发展,脉冲功率电容器的能量存储性能已提升到更高的水平。本研究通过引入Mg0.85Bi0.1ZrO3(MBZ)来改善(Bi0.5Na0.5)0.7Sr0.3TiO3(BNST)陶瓷的能量密度和功率密度(PD)。引入MBZ显著减小了陶瓷晶粒尺寸,并提高了陶瓷的击穿电场(Eb)。在208 kV/cm的电场下,0.90BNST-0.10MBZ陶瓷的可回收储能密度(Wrec)达到2.67 J/cm³,此时极化差值为39.52 μC/cm²,能量存储效率(η)为63.55%。同时,0.90BNST-0.10MBZ陶瓷在20至140 °C的温度范围以及1至200 Hz的频率范围内表现出优异的电学稳定性。此外,在160 kV/cm的电场下,0.90BNST-0.10MBZ陶瓷展现出13.02 MW/cm³的功率密度(PD)和1.368 μs的放电时间。这些特性表明,0.90BNST-0.10MBZ陶瓷在超高功率器件中具有潜在的应用前景。

English Abstract

The performance of pulse power capacitors for energy storage has been elevated to a higher level with the dynamic development of the electronic component industry in recent years. This work improves the energy density and power density ( P D ) in the (Bi 0.5 Na 0.5 ) 0.7 Sr 0.3 TiO 3 (BNST) by introducing Mg 0.85 Bi 0.1 ZrO 3 (MBZ). The ceramic grain size was significantly reduced by the introduction of MBZ, and the breakdown electric field ( E b ) of the ceramics was also enhanced. The recoverable energy storage density ( W rec ) of 0.90BNST-0.10MBZ ceramics is 2.67 J/cm 3 at an electric field of 208 kV/cm, at which time the polarization difference reaches 39.52 μC/cm 2 with an energy storage efficiency ( η ) of 63.55%. Simultaneously, the 0.90BNST-0.10MBZ ceramics exhibit excellent electrical stability under test conditions ranging from 20 to 140 °C and 1 to 200 Hz. Furthermore, the 0.90BNST-0.10MBZ ceramics were found to exhibit a P D of 13.02 MW/cm 3 and a discharge time of 1.368 μs at an electric field of 160 kV/cm. These characteristics indicate that ceramics with 0.90BNST-0.10MBZ have a possible application in exceptionally powerful devices.
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SunView 深度解读

该陶瓷电容储能材料研究对阳光电源ST系列储能变流器和PowerTitan系统具有前瞻价值。其2.67 J/cm³能量密度和13.02 MW/cm³功率密度特性,可为PCS直流侧支撑电容、母线滤波电容提供小型化方案。1.368μs快速放电特性适配SiC/GaN功率器件的高频开关需求,有助于提升三电平拓扑效率。宽温域稳定性(20-140°C)契合储能系统全工况运行要求,可优化iSolarCloud平台的热管理策略,为下一代高功率密度储能系统提供材料技术储备。