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储能系统技术 ★ 5.0

废弃物衍生的rGO掺杂碳酸钙纳米复合材料:一种增强电化学储能的绿色方法

Waste-derived rGO-doped calcium carbonate nanocomposites: a green approach for enhanced electrochemical energy storage

作者 Swaroop Kumar Mandal
期刊 Journal of Materials Science: Materials in Electronics
出版日期 2025年1月
卷/期 第 36.0 卷
技术分类 储能系统技术
相关度评分 ★★★★★ 5.0 / 5.0
关键词 还原氧化石墨烯 碳酸钙 电化学性能 资源化利用 绿色可持续
语言:

中文摘要

实验测定了rGO掺杂CaCO₃纳米复合材料的电化学行为。采用废弃铅笔电池中的石墨棒合成了还原氧化石墨烯(rGO)。该石墨棒不仅用于合成rGO纳米粒子,还有助于废弃物的管理和回收利用。通过一种无化学试剂、无毒、简单且快速的简易技术,将rGO引入碳酸钙(CaCO₃)基体中,制备得到该纳米复合材料。所合成的纳米粒子和纳米复合材料采用场发射扫描电子显微镜(FESEM)和傅里叶变换红外光谱(FTIR)进行了表征。其中,含5% rGO增强的纳米复合材料在1739 cm⁻¹、1421 cm⁻¹和1216 cm⁻¹附近显示出三个明显的特征峰,经FTIR分析得以确认。采用三电极体系进行电化学性能测试。值得注意的是,5% rGO掺杂的纳米复合材料表现出优异的电化学性能,在电流密度分别为2、3、4和5 A/g时,其比电容分别达到55、39、22和14 F/g。

English Abstract

Experimentally, the electrochemical behaviour of rGO-doped CaCO 3 nanocomposite was determined. Reduced graphene oxide (rGO) was synthesized using graphite rod from the waste pencil battery. The graphite rod was used for the synthesis of rGO nanoparticles and also aided in the management and recycling of waste materials. However, the nanocomposite was synthesized by adding rGO into the calcium carbonate (CaCO 3 ) matrix through a simple approach technique that is chemical-free, non-hazardous, simple, and rapid. The synthesized nanoparticles and nanocomposite were characterized using FESEM and FTIR. While the 5% rGO reinforced nanocomposite shows three distinct peaks around 1739 cm −1 , 1421 cm −1 , and 1216 cm −1 confirmed by FTIR analysis. The electrochemical analysis was done using three-electrode methods. Notably, the 5% rGO-doped nanocomposite exhibited excellent electrochemical performance, delivering specific capacitances of 55, 39, 22, and 14 F/g at current densities of 2, 3, 4, and 5 A/g, respectively.
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SunView 深度解读

该废弃材料衍生的rGO-CaCO3纳米复合材料研究为阳光电源储能系统提供了绿色电极材料创新思路。其55 F/g比电容性能可应用于ST系列PCS的超级电容模块优化,提升PowerTitan储能系统的功率响应特性。废旧电池石墨回收技术契合ESS全生命周期绿色理念,可探索退役储能设备材料再利用路径。化学法制备工艺的环保性与快速性为储能电极材料规模化生产提供参考,助力降低储能系统BOM成本,增强市场竞争力。